Peel the sweet potatoes fully, because leftover skin turns tough in the slow cooker. Cut them into 1-inch cubes so they cook evenly. Drop the cubes straight into your 6-quart slow cooker.
In a small bowl, whisk the brown sugar, melted butter, vanilla, and water together. Add the cinnamon, pumpkin pie spice, and a pinch of salt. Stir until the mixture looks smooth and glossy.
Pour the sauce over the sweet potatoes. Stir well with a big spoon so every cube gets coated. This step is what gives you crockpot sweet potatoes with brown sugar and butter flavor in every bite.
Cover the slow cooker with the lid. Cook on high for 4 hours or on low for 8 hours. The potatoes are ready when a fork slides in with no resistance.
Use a potato masher right in the slow cooker. Mash until the potatoes are creamy, leaving a few small bits if you like some texture. For a silkier result, use a hand mixer or an immersion blender.
Mix the brown sugar, melted butter, and chopped pecans in a small bowl. Spread it evenly over the mashed sweet potatoes. Cover and cook for about 5 more minutes, just until the topping melts into a sticky layer.
Turn the slow cooker to warm if guests are not ready yet. Spoon the casserole into a serving dish or serve it straight from the pot. It tastes best hot, with the topping still glossy.